Vol.1 | Issue 1

Cooperativity in non-covalent metallophilic Pt···Pt interaction of aggregated square-planar Pt(II) complexes bearing isoquinolinyl pyrazolate; Theoretical insights

Chattarika Sukpattanacharoen, Prashant Kumar, Nawee Kungwan (NK) *, Daniel Escudero (DE) * / 2020-12-31
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Pt···Pt contacts are more evident in the trimer aggregates rather than in the dimer ones, and especially in the case of the T1 optimized geometries. Esyn and E-EA values indicate a positive synergy between both interactions which is in good agreement with the shortening of the equilibrium distance…